Kevin Sivula
Full Professor
EPFL SB ISIC LIMNO
CH H4 565 (Bâtiment CH)
Station 6
1015 Lausanne
+41 21 693 79 79
+41 21 693 79 78
Office:
CH H4 565
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Web site: Web site: https://limno.epfl.ch/
Web site: Web site: https://www.epfl.ch/schools/sb/scgc/
Web site: Web site: https://isic.epfl.ch/
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limno.epfl.chPublications
Infoscience publications
Automatic extraction from Infoscience:
Improving the photoelectrocatalytic efficiency of CuWO4 through molybdenum for tungsten substitution and coupling with BiVO4
Sustainable Energy & Fuels. 2024-06-14. DOI : 10.1039/d4se00161c.Assessing the Charge Carrier Dynamics at Hybrid Interfaces of Organic Photoanodes for Solar Fuels
Journal Of Physical Chemistry Letters. 2024-06-10. DOI : 10.1021/acs.jpclett.4c01170.Supramolecular interactions using β-cyclodextrin in controlling perovskite solar cell performance
Journal Of Materials Chemistry A. 2024-05-23. DOI : 10.1039/d4ta01741b.Methylammonium Nitrate-Mediated Crystal Growth and Defect Passivation in Lead Halide Perovskite Solar Cells
Acs Energy Letters. 2024-04-12. DOI : 10.1021/acsenergylett.4c00154.Interfacial engineering through lead binding using crown ethers in perovskite solar cells
Journal Of Energy Chemistry. 2024-02-09. DOI : 10.1016/j.jechem.2024.01.042.Inducing porosity in xylose-derived FeNC electrocatalysts for alkaline oxygen reduction
Green Chemistry. 2024-02-02. DOI : 10.1039/d3gc04645a.Composition-tunable transition metal dichalcogenide nanosheets via a scalable, solution-processable method
Nanoscale Horizons. 2024-01-30. DOI : 10.1039/d3nh00477e.Green hydrogen production using Shewanella oneidensis MR-1 bioanode and cuprous oxide-based photocathode
Lausanne, EPFL, 2024. DOI : 10.5075/epfl-thesis-10613.Efficient Cu2O Photocathodes for Aqueous Photoelectrochemical CO2 Reduction to Formate and Syngas
Journal Of The American Chemical Society. 2023-12-13. DOI : 10.1021/jacs.3c06146.Ink-Based CuIn0.3Ga0.7S2 Nanocrystal Thin Films as Photocathodes for Photoelectrochemical CO2 Reduction Reaction
Acs Applied Nano Materials. 2023-06-13. DOI : 10.1021/acsanm.3c00836.Edge-Sharing Octahedrally Coordinated Ni-Fe Dual Active Sites on ZnFe2O4 for Photoelectrochemical Water Oxidation
Advanced Science. 2023-06-01. DOI : 10.1002/advs.202301869.Understanding and Mitigating the Degradation of Perovskite Solar Cells Based on a Nickel Oxide Hole Transport Material during Damp Heat Testing
Acs Applied Materials & Interfaces. 2023-05-31. DOI : 10.1021/acsami.3c02709.Photogenerated charge transfer in Dion-Jacobson type layered perovskite based on naphthalene diimide
Chemical Science. 2023-05-15. DOI : 10.1039/d3sc00783a.Do You Really Mean to Call It Highly Efficient?
Acs Energy Letters. 2023-05-12. DOI : 10.1021/acsenergylett.3c00772.Surface Passivation of FAPbI3-Rich Perovskite with Cesium Iodide Outperforms Bulk Incorporation
ACS Energy Letters. 2023-05-04. DOI : 10.1021/acsenergylett.3c00609.Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells
Nature Energy. 2023-04-17. DOI : 10.1038/s41560-023-01249-0.Assembling a Photoactive 2D Puzzle: From Bulk Powder to Large- Area Films of Semiconducting Transition-Metal Dichalcogenide Nanosheets
Accounts Of Materials Research. 2023-03-15. DOI : 10.1021/accountsmr.2c00209.Photoelectrochemical CO2 Reduction at a Direct CuInGaS2/Electrolyte Junction
Acs Energy Letters. 2023-03-02. DOI : 10.1021/acsenergylett.3c00022.Enabling Direct Photoelectrochemical H2 Production Using Alternative Oxidation Reactions on WO3
Chimia. 2023-03-01. DOI : 10.2533/chimia.2023.110.Transparent Porous Conductive Substrates for Gas-Phase Photoelectrochemical Hydrogen Production
Advanced Materials. 2023-01-02. DOI : 10.1002/adma.202208740.Precious metal-free (photo)electrochemistry for green hydrogen production
Lausanne, EPFL, 2023. DOI : 10.5075/epfl-thesis-10166.Photoelectrochemical Cell Engineering for Solar Energy Conversion
Lausanne, EPFL, 2023. DOI : 10.5075/epfl-thesis-10560.Materials engineering for improved stability of perovskite solar cells
Lausanne, EPFL, 2023. DOI : 10.5075/epfl-thesis-10636.Synthesis and Characterization of Functionalized Spacer Cations for the Incorporation in Layered Perovskites
Lausanne, EPFL, 2023. DOI : 10.5075/epfl-thesis-10451.Tungsten oxide-based photoanodes: biomass valorization and the effects of oxygen vacancies
Lausanne, EPFL, 2023. DOI : 10.5075/epfl-thesis-9453.Effects of surface wettability on (001)-WO3 and (100)-WSe2: A spin-polarized DFT-MD study
Applied Surface Science. 2022-11-01. DOI : 10.1016/j.apsusc.2022.154203.Light-Responsive Oligothiophenes Incorporating Photochromic Torsional Switches
Chemistry-A European Journal. 2022-10-31. DOI : 10.1002/chem.202202698.An Organic Semiconductor Photoelectrochemical Tandem Cell for Solar Water Splitting
Advanced Energy Materials. 2022-09-08. DOI : 10.1002/aenm.202202363.Covalent Organic Framework Nanoplates Enable Solution-Processed Crystalline Nanofilms for Photoelectrochemical Hydrogen Evolution
Journal Of The American Chemical Society. 2022-06-15. DOI : 10.1021/jacs.2c0143310291.Multiple Effects Induced by Mo6+ Doping in BiVO4 Photoanodes
Solar Rrl. 2022-06-15. DOI : 10.1002/solr.202200349.Transparency and Morphology Control of Cu2O Photocathodes via an in Situ Electroconversion
ACS Energy Letters. 2022-04-07. DOI : 10.1021/acsenergylett.2c00474.Tuning Napththalenediimide Cations for Incorporation into Ruddlesden–Popper-Type Hybrid Perovskites
Chemistry of Materials. 2022-04-07. DOI : 10.1021/acs.chemmater.2c00246.High Performance Semiconducting Nanosheets via a Scalable Powder-Based Electrochemical Exfoliation Technique
Acs Nano. 2022-03-15. DOI : 10.1021/acsnano.1c10739.Bulk Heterojunction Organic Semiconductor Photoanodes: Tuning Energy Levels to Optimize Electron Injection
Acs Applied Materials & Interfaces. 2022-02-07. DOI : 10.1021/acsami.1c21440.Derivative voltammetry: a simple tool to probe reaction selectivity in photoelectrochemical cells
Sustainable Energy & Fuels. 2022. DOI : 10.1039/D2SE00692H.Semiconducting two dimensional transition metal dichalcogenides via solution-processable routes
Lausanne, EPFL, 2022. DOI : 10.5075/epfl-thesis-9099.Engineering of PEM-PEC photocathodes for solar-driven hydrogen production
Lausanne, EPFL, 2022. DOI : 10.5075/epfl-thesis-9902.Exploring new avenues for perovskite photovoltaics: Molecular functionalization of layered lead-halide perovskites and defect mitigation in lead-free double perovskites
Lausanne, EPFL, 2022. DOI : 10.5075/epfl-thesis-9434.Organic Semiconductors For Photoelectrochemical Applications
Lausanne, EPFL, 2022. DOI : 10.5075/epfl-thesis-8769.Key factors boosting the performance of planar ZnFe2O4 photoanodes for solar water oxidation
Journal Of Materials Chemistry A. 2021-12-07. DOI : 10.1039/d1ta07499g.Identifying Reactive Sites and Surface Traps in Chalcopyrite Photocathodes
Angewandte Chemie-International Edition. 2021-10-01. DOI : 10.1002/anie.202108994.Mott–Schottky Analysis of Photoelectrodes: Sanity Checks Are Needed
ACS Energy Letters. 2021-07-09. DOI : 10.1021/acsenergylett.1c01245.Benzodithiophene‐Based Spacers for Layered and Quasi‐Layered Lead Halide Perovskite Solar Cells
ChemSusChem. 2021-06-21. DOI : 10.1002/cssc.202100992.Spray Synthesis of CuFeO2 Photocathodes and In-Operando Assessment of Charge Carrier Recombination
Journal Of Physical Chemistry C. 2021-05-27. DOI : 10.1021/acs.jpcc.1c02282.A semiconducting polymer bulk heterojunction photoanode for solar water oxidation
Nature Catalysis. 2021-05-01. DOI : 10.1038/s41929-021-00617-x.A hybrid bulk-heterojunction photoanode for direct solar-to-chemical conversion dagger
Energy & Environmental Science. 2021-03-30. DOI : 10.1039/d1ee00152c.Organic Semiconductors as Photoanodes for Solar-driven Photoelectrochemical Fuel Production
Chimia. 2021-03-01. DOI : 10.2533/chimia.2021.169.A Direct Z-Scheme for the Photocatalytic Hydrogen Production from a Water Ethanol Mixture on CoTiO3/TiO2 Heterostructures
Acs Applied Materials & Interfaces. 2021-01-13. DOI : 10.1021/acsami.0c17004.Systematic investigations of uranium carbide composites oxidation from micro- to nano-scale: Application to waste disposal
Lausanne, EPFL, 2021. DOI : 10.5075/epfl-thesis-8234.Novel Interfacial Characterization and Surface Engineering in Semiconductor Electrodes for Optimized Solar Fuel Production
Lausanne, EPFL, 2021. DOI : 10.5075/epfl-thesis-8554.Direct photoelectrochemical oxidation of hydroxymethylfurfural on tungsten trioxide photoanodes
RSC Advances. 2021. DOI : 10.1039/D0RA09989A.Spectroelectrochemical and Chemical Evidence of Surface Passivation at Zinc Ferrite (ZnFe 2 O 4 ) Photoanodes for Solar Water Oxidation
Advanced Functional Materials. 2021. DOI : 10.1002/adfm.202010081.Defect engineered nanostructured LaFeO3 photoanodes for improved activity in solar water oxidation
Journal of Materials Chemistry. 2021. DOI : 10.1039/D0TA11541J.Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells
Journal Of The American Chemical Society. 2020-11-25. DOI : 10.1021/jacs.0c08592.Influence of Composition on Performance in Metallic Iron-Nickel-Cobalt Ternary Anodes for Alkaline Water Electrolysis
Acs Catalysis. 2020-10-16. DOI : 10.1021/acscatal.0c03523.MIL-101(Fe)/g-C3N4 for enhanced visible-light-driven photocatalysis toward simultaneous reduction of Cr(VI) and oxidation of bisphenol A in aqueous media
Applied Catalysis B-Environmental. 2020-09-05. DOI : 10.1016/j.apcatb.2020.119033.Passivation Mechanism Exploiting Surface Dipoles Affords High-Performance Perovskite Solar Cells
Journal Of The American Chemical Society. 2020-07-01. DOI : 10.1021/jacs.0c01704.Generalized Synthesis to Produce Transparent Thin Films of Ternary Metal Oxide Photoelectrodes
Chemsuschem. 2020-06-04. DOI : 10.1002/cssc.202000926.Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper-iron oxide|TiO2-cobaloxime photocathode
Green Chemistry. 2020-05-21. DOI : 10.1039/d0gc00979b.Understanding Surface Recombination Processes Using Intensity-Modulated Photovoltage Spectroscopy on Hematite Photoanodes for Solar Water Splitting
Helvetica Chimica Acta. 2020-05-07. DOI : 10.1002/hlca.202000064.FeO-based nanostructures and nanohybrids for photoelectrochemical water splitting
Progress In Materials Science. 2020-05-01. DOI : 10.1016/j.pmatsci.2019.100632.Establishing Stability in Organic Semiconductor Photocathodes for Solar Hydrogen Production
Journal Of The American Chemical Society. 2020-04-29. DOI : 10.1021/jacs.0c00126.Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks
Chemical Science. 2020-04-28. DOI : 10.1039/d0sc00740d.Hydrogenation of ZnFe2O4 Flat Films: Effects of the Pre-Annealing Temperature on the Photoanodes Efficiency for Water Oxidation
Surfaces. 2020-03-12. DOI : 10.3390/surfaces3010009.Cu2O photocathodes with band-tail states assisted hole transport for standalone solar water splitting
Nature Communications. 2020-01-16. DOI : 10.1038/s41467-019-13987-5.Roll-to-Roll Deposition of Semiconducting 2D Nanoflake Films of Transition Metal Dichalcogenides for Optoelectronic Applications
ACS Applied Nano Materials. 2019-11-17. DOI : 10.1021/acsanm.9b01774.In Situ Electrochemical Oxidation of Cu2S into CuO Nanowires as a Durable and Efficient Electrocatalyst for Oxygen Evolution Reaction
Chemistry Of Materials. 2019-09-24. DOI : 10.1021/acs.chemmater.9b02790.Multiarm and Substituent Effects on Charge Transport of Organic Hole Transport Materials
Chemistry of Materials. 2019-09-10. DOI : 10.1021/acs.chemmater.9b00438.Robust Electron Transport Layers via In Situ Cross-Linking of Perylene Diimide and Fullerene for Perovskite Solar Cells
ACS Applied Energy Materials. 2019-09-01. DOI : 10.1021/acsaem.9b01154.In situ and operando spectroelectrochemical techniques for evaluating interfacial carrier behavior in emerging photoelectrodes for solar fuel production
2019-08-25. Fall National Meeting and Exposition of the American-Chemical-Society (ACS), San Diego, CA, Aug 25-29, 2019.Lead Halide Perovskite Quantum Dots to Enhance the Power Conversion Efficiency of Organic Solar Cells
Angewandte Chemie-International Edition. 2019-08-01. DOI : 10.1002/anie.201906803.Porous NiTiO3/TiO2 nanostructures for photocatatalytic hydrogen evolution
Journal Of Materials Chemistry A. 2019-07-28. DOI : 10.1039/c9ta04763h.Solution-Processed Ultrathin SnS2-Pt Nanoplates for Photoelectrochemical Water Oxidation
Acs Applied Materials & Interfaces. 2019-02-20. DOI : 10.1021/acsami.8b17622.Insights into the interfacial carrier behaviour of copper ferrite ( CuFe2O4) photoanodes for solar water oxidation
Journal Of Materials Chemistry A. 2019-01-28. DOI : 10.1039/c8ta11160j.Covalent polymer network semiconducting thin-films and method for producing thereof
WO2019145025 . 2019.Alternative Oxidation Reactions for Solar-Driven Fuel Production
ACS Catalysis. 2019. DOI : 10.1021/acscatal.8b04565.Fully Conjugated Donor–Acceptor Block Copolymers for Organic Photovoltaics via Heck–Mizoroki Coupling
ACS Macro Letters. 2019. DOI : 10.1021/acsmacrolett.8b00932.Organic Semiconductor Based Devices for Solar Water Splitting
Advanced Energy Materials. 2018-11-15. DOI : 10.1002/aenm.201802585.A Step toward Economically Viable Solar Fuel Production
Chem. 2018-11-08. DOI : 10.1016/j.chempr.2018.10.015.Nanocrystalline Boron-Doped Diamond as a Corrosion-Resistant Anode for Water Oxidation via Si Photoelectrodes
Acs Applied Materials & Interfaces. 2018-09-05. DOI : 10.1021/acsami.8b08714.Defect engineering of liquid phase exfoliated 2D semiconducting WSe2 nanoflakes for solar fuel generation
2018-08-19. 256th National Meeting and Exposition of the American-Chemical-Society (ACS) - Nanoscience, Nanotechnology and Beyond, Boston, MA, Aug 19-23, 2018.Conjugation break spacers and flexible linkers as tools to engineer the properties of semiconducting polymers
2018-08-19. 256th National Meeting and Exposition of the American-Chemical-Society (ACS) - Nanoscience, Nanotechnology and Beyond, Boston, MA, Aug 19-23, 2018.Conjugation break spacers and flexible linkers as tools to engineer the properties of semiconducting polymers
POLYMER JOURNAL. 2018. DOI : 10.1038/s41428-018-0069-z.Photocatalytic hydrogen generation from a visible-light responsive metal–organic framework system: the impact of nickel phosphide nanoparticles
Journal of Materials Chemistry. 2018-10-18. DOI : 10.1039/C7TA10225A.Iron-Rich Natural Mineral Gibeon Meteorite Catalyzed N -formylation of Amines using CO2 as the C1 Source
ChemistrySelect. 2018. DOI : 10.1002/slct.201802646.Spinel Structural Disorder Influences Solar-Water-Splitting Performance of ZnFe2 O4 Nanorod Photoanodes
Advanced Materials. 2018. DOI : 10.1002/adma.201801612.Melt-processing of small molecule organic photovoltaics via bulk heterojunction compatibilization
Green Chemistry. 2018. DOI : 10.1039/C8GC00335A.Molecular Engineering Strategies for Morphology Control in Organic Semiconductors for Optoelectronics
Lausanne, EPFL, 2018. DOI : 10.5075/epfl-thesis-8520.Design and validation of a foldable and photovoltaic wide-field epiretinal prosthesis
Nature Communications. 2018-03-08. DOI : 10.1038/s41467-018-03386-7.Catalyst-Free, Fast, and Tunable Synthesis for Robust Covalent Polymer Network Semiconducting Thin Films
Advanced Functional Materials. 2018. DOI : 10.1002/adfm.201706303.Defect Mitigation of Solution-Processed 2D WSe2 Nanoflakes for Solar-to-Hydrogen Conversion
Nano Letters. 2018. DOI : 10.1021/acs.nanolett.7b03948.Evaluating spinel ferrites MFe2O4 (M = Cu, Mg, Zn) as photoanodes for solar water oxidation: prospects and limitations
Sustainable Energy & Fuels. 2018. DOI : 10.1039/C7SE00448F.Potential-sensing electrochemical atomic force microscopy for in operando analysis of water-splitting catalysts and interfaces
Nature Energy. 2018. DOI : 10.1038/s41560-017-0048-1.The Many Faces of Mixed Ion Perovskites: Unraveling and Understanding the Crystallization Process
Acs Energy Letters. 2017. DOI : 10.1021/acsenergylett.7b00981.Design and validation of a foldable and photovoltaic wide-field epiretinal prosthesis
2017 Artificial Vision Meeting, Aachen, Germany, December 1-2, 2017.Design and validation of a foldable and photovoltaic wide-field retinal prosthesis
2017 MRS Fall Meeting, Boston, Massachusetts, USA, November 26-December 1, 2017.Demonstration and Characterization of Ladder-Type Conjugated Polymer Photoanode for Direct Light-Driven Water Oxidation
Lausanne, EPFL, 2017. DOI : 10.5075/epfl-thesis-7975.Photogenerated Charge Harvesting and Recombination in Photocathodes of Solvent-Exfoliated WSe2
Chemistry Of Materials. 2017. DOI : 10.1021/acs.chemmater.7b02018.Amorphous Ternary Charge-Cascade Molecules for Bulk Heterojunction Photovoltaics
Acs Applied Materials & Interfaces. 2017. DOI : 10.1021/acsami.7b04983.Morphology stabilization strategies for small-molecule bulk heterojunction photovoltaics
Journal Of Materials Chemistry A. 2017. DOI : 10.1039/c7ta05405j.Other publications
Teaching & PhD
Teaching
Chemistry and Chemical Engineering
PhD Students
Alsabeh Ghewa, Bouchez Arthur Eliot, Diercks Nicolas Johannes, Foltzer-De Cian Louise Marie, Goldman Benjamin, Jeanguenat Colin, Jiajun Li, Johanning Melanie Victoria,Past EPFL PhD Students
Bin Rahmanudin Hamdan Muhammad Aiman , Bornoz Pauline , Brillet Jérémie Minh-Châu , Caretti Marina Caroline Michèle , Cornuz Maurin , Firth Connor Robert , Gasperini Andrea , Jeanbourquin Xavier Adrian , Johnson Hannah Elizabeth , Kim Yeonju , Liu Yongpeng , Morgante Michele , Nussbaum Simon , Plainpan Nukorn , Primera Darwich Barbara Alexandra , Prévot Mathieu Steven , Schreier Marcel Roland , Sekar Arvindh , Steier Ludmilla , Vuong Nhât-Tân , Wells Rebekah Anne , Xia Meng , Yu Xiaoyun , Zhang Dan ,Courses
Numerical methods
This course introduces students to modern computational and mathematical techniques for solving problems in chemistry and chemical engineering. The use of introduced numerical methods will be demonstrated using the python programming language.
Fluid mechanics and transport phenomena
The concept of Shell balances, the Navier-Stokes equations and generalized differential balances equations for heat and mass transport are derived. These relations are applied to model systems. Integral balances are introduced in the context of boundary layers and transfer coefficients.
Chemical engineering product design
Chemical product design has become more important because of major changes in the chemical industry. This course presents the basic method for chemical product design and gives direct practice to this procedure via a design project.