Oleg Boyarkine

Maître d'enseignement et de recherche
oleg.boiarkin@epfl.ch +41 21 693 30 38
Nationalité : swiss/russian
EPFL SB ISIC LCPM
CH F1 497 (Bâtiment CH)
Station 6
CH-1015 Lausanne
Web site: Site web: https://lcpm.epfl.ch
+41 21 693 30 38
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Biography
EDUCATIONPh.D., Chemical Physics, Research Centre for Technological Lasers of USSR Academy of Science, Moscow, USSR, May 1991.
Diploma in Chemical Physics, Moscow Physical Technical Institute, Moscow, USSR, 1978-1984.
RESEARCH EXPERIENCE
1994-currently Laboratory of Molecular Chemical Physics, Ecole Polytechnique Fédérale de Lausanne, Switzerland. Senior research scientist.
Vibrational/electronic spectroscopy of protonated cold large biological molecules in gas-phase.
Double/triple resonance vibrational overtone spectroscopy of gas phase water up to dissociation threshold.
Double resonance laser isotope separation. Specific properties of IR MPD are employed for highly selective isotope separation on molecules, particular for carbon and silicon isotopes. The US patent # 6,653,587 has been obtained for this technology.
Single/double resonance vibrational overtone spectroscopy of polyatomic molecules cooled in a supersonic jet. Infrared Laser Assisted Photofragment Spectroscopy (IRLAPS) technique, based on infrared multiple photon dissociation (IRMPD) of molecules by CO2 laser, is employed to detect weak overtone transitions.
1992-93 Department of Chemistry, University of Rochester, Rochester, NY, USA. Postdoc. Overtone spectroscopy of polyatomic molecules. IRLAPS detection technique was used for vibrational overtone spectroscopy of jet-cooled molecules.
1986-92 Research Centre for Technological Lasers of USSR Academy of Science, Moscow, Russia. Research engineer to research scientist. Ph.D. research: Infrared absorption spectroscopy of vibrationally excited jet-cooled polyatomic molecules using an original infrared photo-dissociation technique.
1990-91 Asteroid LTD. Head of research division Lasers and applications. The first soviet commercial high rep. rate, high energy excimer laser has been developed, built and sold.
1984 -86 Institute of Chemical Physics of USSR Academy of Science, Moscow. Engineer. Research with Prof. N. N. Semenov. Long-time quenching of chains in reaction F2+H2 inhibited by O2. HF products of the laser induced reaction were detected by MS.
TEACHING EXPERIENCE
2010- Practical works for 2nd semester students " Chemistry for physicists"
2005-currently: Charge de course at EPFL. Lecturing a Master course for the 4th year students: Lasers and their applications in chemistry (28 hours),
1995- currently: Training and guiding PhD (6) and diploma (2) students,
1995-1998 developing and conducting practical work for the 7th semester students;
Patent
T. Rizzo, O. Boiarkine, Laser Separation Method Employing Isotopically Selective Collisional Relaxation, US patent # 6,653,587 B1. Accepted: 2003, priority date 1999.Old publications
1. O.V. Boyarkin, S.I. Ionov, V.N. Bagratashvili, "IR spectroscopy and dynamics of strongly vibrationally excited polyatomic molecules: CF3I." Chem.Phys.Letters 146,106 (1988).2. O.V. Boyarkin, S.I. Ionov, A.A. Kobakhidze, "IR spectroscopy of polyatomic molecules, vibrationally excited above the dissociation threshold: C2F5I, C3F7I and n-C4F9I.", Spectrochimica Acta 46A, 537 (1990).
3. O.V. Boyarkin, S.I. Ionov, A.A. Stuchebrukhov, M.S. Djidjoev, V.N. Bagratashvili, "IR spectrum of vibrationally excited OsO4 in the region of strong nonlinear interaction of vibrational modes.", J. Phys. Chem. 94, 1294 (1990).
4. O.V. Boyarkin, G.A. Kapralova, A.M. Chaikin, "About length of chain in reaction of fluorine and hydrogen.", Khim. Fizika 9, 1375 (1990) (in Russian).
5. O.V. Boyarkin, S.I. Ionov, A.A. Stuchebrukhov, M.S. Djidjoev, V.N. Bagratashvili, "IR spectroscopy of high-lying states of vibrational quasi-continuum of OsO4 molecule.", Khim. Fiz 10, 1155 (1991) (in Russian).
6. O.V. Boyarkin, "Possibility of isotope selective influence by laser radiation on molecules, excited into vibrational quasicontinuum.", Khim. Fizika 11, 1021 (1992) (in Russian).
7. O.V. Boyarkin, V.N. Bagratashvili, C. Angelie "Photodissociation IR spectroscopy of vibrationally highly excited 13CF3I. Influence of isotopic substitution.", J. Phys. B 25, 4487 (1992).
8. O.V. Boyarkin, V.N. Burimov, V.S. Golybev, A.N. Zherihin, V.L. Popkov "Velocity distribution of Yttrium, occuring under laser ablation of YBa2Cu3O7-x target.", Izvestiya Academii Nayk, ser. Fizicheskaya 57, 90 (1993) (in Russian).
9. A. Kholkin, O. Boiarkine, N. Setter "Transient photocurrents in lead zirconate titanate thin films", Appl. Phys. Lett. 72, 130 (1998).
Publications
Publications Infoscience
Microhydration of Biomolecules: Revealing the Native Structures by Cold Ion IR Spectroscopy
The Journal of Physical Chemistry Letters. 2021-01-13. DOI : 10.1021/acs.jpclett.0c03678.Identification and Quantification of Any Isoforms of Carbohydrates by 2D UV-MS Fingerprinting of Cold Ions
Analytical Chemistry. 2020-11-03. DOI : 10.1021/acs.analchem.0c03122.Revealing Single-Bond Anomeric Selectivity in Carbohydrate-Protein Interactions
Journal Of Physical Chemistry Letters. 2020-05-07. DOI : 10.1021/acs.jpclett.0c00871.Ultraviolet Photodissociation of Peptides: New Insight on the Mobile Proton Model
Journal Of Experimental And Theoretical Physics. 2020-04-01. DOI : 10.1134/S1063776120030164.Spectroscopic Evidence for Peptide-Bond-Selective Ultraviolet Photodissociation
The Journal of Physical Chemistry Letters. 2020. DOI : 10.1021/acs.jpclett.9b03221.Gas-phase structures reflect the pain-relief potency of enkephalin peptides
Physical Chemistry Chemical Physics. 2019-09-24. DOI : 10.1039/C9CP04098F.Interplay of H-Bonds with Aromatics in Isolated Complexes Identifies Isomeric Carbohydrates
Angewandte Chemie-International Edition. 2019-05-27. DOI : 10.1002/anie.201902377.Method for Identification of Threonine Isoforms in Peptides by Ultraviolet Photofragmentation of Cold Ions
Analytical Chemistry. 2019-05-21. DOI : 10.1021/acs.analchem.9b00770.Cold ion spectroscopy for structural identifications of biomolecules
International Reviews in Physical Chemistry. 2018-12-07. DOI : 10.1080/0144235X.2018.1547453.Intrinsic structure of pentapeptide Leu-enkephalin: geometry optimization and validation by comparison of VSCF-PT2 calculations with cold ion spectroscopy
Phys. Chem. Chem. Phys.. 2018-09-07. DOI : 10.1039/C8CP03989E.Peptide Bond Ultraviolet Absorption Enables Vibrational Cold-Ion Spectroscopy of Nonaromatic Peptides
The Journal of Physical Chemistry Letters. 2018-08-29. DOI : 10.1021/acs.jpclett.8b02148.Identification of isoforms of aspartic acid residues in peptides by 2D UV-MS fingerprinting of cold ions
The Analyst. 2018-07-06. DOI : 10.1039/C7AN02044A.Initial Steps of Amyloidogenic Peptide Assembly Revealed by Cold-Ion Spectroscopy
Angewandte Chemie-International Edition. 2018. DOI : 10.1002/anie.201710188.High Susceptibility of Histidine to Charge Solvation Revealed by Cold Ion Spectroscopy
Angewandte Chemie-International Edition. 2017. DOI : 10.1002/anie.201709437.A Decapeptide Hydrated by Two Waters: Conformers Determined by Theory and Validated by Cold Ion Spectroscopy
Journal Of Physical Chemistry A. 2017. DOI : 10.1021/acs.jpca.7b10357.Multilaser Conformer-Selective Spectroscopy of Cold Biomolecular Ions in the Gas Phase
Lausanne, EPFL, 2017. DOI : 10.5075/epfl-thesis-8012.Exploring the relevance of gas-phase structures to biology: cold ion spectroscopy of the decapeptide neurokinin A
Physical Chemistry Chemical Physics -Cambridge- Royal Society of Chemistry. 2017. DOI : 10.1039/c6cp07953a.Identification of Isomeric Ephedrines by Cold Ion UV Spectroscopy: Toward Practical Implementation
Analytical Chemistry. 2017. DOI : 10.1021/acs.analchem.6b04182.Method and apparatus for the analysis of molecules using mass spectrometry and optical spectroscopy
US2020152435 ; US10546737 ; US2019244798 ; CN107529342 ; US10283336 ; GB2531336 ; JP6445154 ; CN107529342 ; JP2017532563 ; US2017243728 ; EP3207556 ; WO2016059037 ; GB2531336 ; GB201418436 . 2016.Novel Approaches in Cold Ion Spectroscopy for Structural Characterization of Biomolecules in the Gas Phase
Lausanne, EPFL, 2016. DOI : 10.5075/epfl-thesis-7117.Vibrational Signatures of Conformer-Specific Intramolecular Interactions in Protonated Tryptophan
Journal of Physical Chemistry A. 2016. DOI : 10.1021/acs.jpca.6b05605.Nonstatistical UV Fragmentation of Gas-Phase Peptides Reveals Conformers and Their Structural Features
Journal of physical chemistry letters. 2016. DOI : 10.1021/acs.jpclett.6b00292.Resonance Energy Transfer Relates the Gas-Phase Structure and Pharmacological Activity of Opioid Peptides
Angewandte Chemie -International Edition in English-. 2016. DOI : 10.1002/anie.201508915.Colors for Molecular Masses: Fusion of Spectroscopy and Mass Spectrometry for Identification of Biomolecules
Analytical Chemistry. 2015. DOI : 10.1021/acs.analchem.5b00822.Dissociation threshold of H218O: Validating ab initio calculations by state-selective triple-resonance spectroscopy
Chemical Physics Letters. 2015. DOI : 10.1016/j.cplett.2015.03.036.Conformational Structures of a Decapeptide Validated by First Principles Calculations and Cold Ion Spectroscopy
Chemphyschem. 2015. DOI : 10.1002/cphc.201500085.Cryogenic Methods for the Spectroscopy of Large, Biomolecular Ions
Gas-phase IR Spectroscopy for the Structural Characterization of Biomolecules; Berlin: Springer, 2015. p. 43-97.Fragmentation mechanism of UV-excited peptides in the gas phase
Journal of Chemical Physics. 2014. DOI : 10.1063/1.4897158.Identification of Tyrosine-Phosphorylated Peptides Using Cold Ion Spectroscopy
Journal of the American Chemical Society. 2014. DOI : 10.1021/ja5053544.Cryogenically cooled octupole ion trap for spectroscopy of biomolecular ions
Review of Scientific Instruments. 2014. DOI : 10.1063/1.4868178.Microhydration Effects on the Encapsulation of Potassium Ion by Dibenzo-18-Crown-6
Journal Of The American Chemical Society. 2014. DOI : 10.1021/ja4086066.Exploring the Mechanism of IR–UV Double-Resonance for Quantitative Spectroscopy of Protonated Polypeptides and Proteins
Angewandte Chemie International Edition. 2013. DOI : 10.1002/anie.201301656.Accurate bond dissociation energy of water determined by triple-resonance vibrational spectroscopy and ab initio calculations
Chemical Physics Letters. 2013. DOI : 10.1016/j.cplett.2013.03.007.Laser Spectroscopic Study of Cold Host–Guest Complexes of Crown Ethers in the Gas Phase
ChemPhysChem. 2013. DOI : 10.1002/cphc.201200746.Assessing the performance of computational methods for the prediction of the ground state structure of a cyclic decapeptide
International Journal of Quantum Chemistry. 2013. DOI : 10.1002/qua.24085.Stark coefficients for highly excited rovibrational states of H2O
Journal of Chemical Physics. 2012. DOI : 10.1063/1.4730295.Global spectroscopy of the water monomer
Philosophical Transactions of the Royal Society of London Series a Mathematical and Physical Sciences. 2012. DOI : 10.1098/rsta.2011.0259.State-resolved spectroscopy of high vibrational levels of water up to the dissociative continuum
Philosophical Transactions of the Royal Society of London Series A: Mathematical and Physical Sciences. 2012. DOI : 10.1098/rsta.2011.0277.Interplay of Intra- and Intermolecular H-Bonding in a Progressively Solvated Macrocyclic Peptide
Science. 2012. DOI : 10.1126/science.1218709.Ion Selectivity of Crown Ethers Investigated by UV and IR Spectroscopy in a Cold Ion Trap
Journal of Physical Chemistry A. 2012. DOI : 10.1021/jp3011519.Conformational distribution of bradykinin [bk+2H]2+ revealed by cold ion spectroscopy coupled with FAIMS
Journal of the American Society for Mass Spectrometry. 2012. DOI : 10.1007/s13361-012-0384-0.UV and IR spectroscopy of cold 1,2-dimethoxybenzene complexes with alkali metal ions
Physical Chemistry Chemical Physics. 2012. DOI : 10.1039/C2CP24018A.Conformation-Specific Spectroscopy of Peptide Fragment Ions in a low-Temperature Ion Trap
JASMS. 2012. DOI : 10.1007/s13361-012-0368-0.Conformation-specific infrared spectroscopy of gas phase peptides in a cold ion trap
2011. 241st National Meeting and Exposition of the American-Chemical-Society (ACS), Anaheim, CA, Mar 27-31, 2011. p. 83-PHYS.Cold Ion Spectroscopy of Biological Molecules in the Gas Phase
Lausanne, EPFL, 2011. DOI : 10.5075/epfl-thesis-5252.Cold Ion Spectroscopy Reveals the Intrinsic Structure of a Decapeptide
Angewandte Chemie, International Edition. 2011. DOI : 10.1002/anie.201100702.Spectroscopy of mobility-selected biomolecular ions
Faraday Discussions. 2011. DOI : 10.1039/C0FD00004C.UV Spectroscopic Studies of Cold Alkali Metal Ion–Crown Ether Complexes in the Gas Phase
Journal of the American Chemical Society. 2011. DOI : 10.1021/ja2046205.Using differential ion mobility as a conformational filter for cold ion spectroscopy
2010. p. 311-PHYS.Fragmentation mechanisms of electronically excited peptides in a cold ion trap
2010. p. 176-PHYS.Communication: Feshbach resonances in the water molecule revealed by state-selective spectroscopy (vol 133, 081103, 2010)
Journal Of Chemical Physics. 2010. DOI : 10.1063/1.3504864.Structure and Bonding of Isoleptic Coinage Metal (Cu, Ag, Au) Dimethylaminonitrenes in the Gas Phase
Journal of the American Chemical Society. 2010. DOI : 10.1021/ja104649k.Quantitative State-Selective Spectroscopy of Water Below and Above the First Dissociation Limit
Lausanne, EPFL, 2010. DOI : 10.5075/epfl-thesis-4843.Feshbach resonances in the water molecule revealed by state-selective spectroscopy
Journal of Chemical Physics. 2010. DOI : 10.1063/1.3472312.A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions
Review of Scientific Instruments. 2010. DOI : 10.1063/1.3458014.Highly-resolved Spectra of Gas-phase Gramicidin S: A Benchmark for Peptide Structure Calculations
Journal of the American Chemical Society. 2010. DOI : 10.1021/ja910118j.State-selective spectroscopy of water up to its first dissociation limit
Journal of Chemical Physics. 2009. DOI : 10.1063/1.3273207.Spectroscopic studies of cold, gas-phase biomolecular ions
International Reviews in Physical Chemistry. 2009. DOI : 10.1080/01442350903069931.Spectroscopy of Protonated Peptides Assisted by Infrared Multiple Photon Excitation
Journal of Physical Chemistry A. 2009. DOI : 10.1021/jp811243w.Spectroscopy and Conformational Preferences of Gas-Phase Helices
Physical Chemistry Chemical Physics. 2009. DOI : 10.1039/b814143f.Spectroscopic probes of cold, gas-phase biomolecular ions: From amino acids to helical peptides
2008. 236th National Meeting of the American-Chemical-Society, Philadelphia, PA, Aug 17-21, 2008. p. 12-PHYS.Collisionally-assisted spectroscopy of water from 27000 to 34000 cm-1
Journal of Physical Chemistry A. 2008. DOI : 10.1021/jp805849q.Effects of N-terminus substitution on the structure and spectroscopy of gas-phase helices
Chimia. 2008. DOI : 10.2533/chimia.2008.240.Multiple-resonance spectroscopy of high vibrational levels in water and methanol
Lausanne, EPFL, 2008. DOI : 10.5075/epfl-thesis-4067.Laser isotope separation method employing isotopically selective collisional relaxation
EP1742720 ; US6653587 ; JP2003505242 ; WO0108788 ; AU4423800 ; WO0108788 ; EP1072303 . 2007.Spectroscopic signatures of gas-phase helices: Ac-Phe-(Ala)5-Lys-H+ and Ac-Phe-(Ala)10-Lys-H+
Journal of the American Chemical Society. 2007. DOI : 10.1021/ja076507s.Conformation-specific infrared and ultraviolet spectroscopy of tyrosine-based protonated dipeptides
Journal of Chemical Physics. 2007. DOI : 10.1063/1.2798111.Conformation-specific spectroscopy and photodissociation of cold, protonated tyrosine and phenylalanine
Journal of the American Chemical Society. 2007. DOI : 10.1021/ja0736010.Approaching the full set of energy levels of water
Journal of Chemical Physics. 2007. DOI : 10.1063/1.2748751.Isotopically selective collisional vibrational energy transfer in CF3H
Journal of Chemical Physics. 2007. DOI : 10.1063/1.2433946.Conformational dependence of intramolecular vibrational redistribution in methanol
Journal of Chemical Physics. 2007. DOI : 10.1063/1.2431367.Microsolvation effects on the excited state dynamics of protonated tryptophan
Journal of the American Chemical Society. 2006. DOI : 10.1021/ja065980n.A direct measurement of the dissociation energy of water
Journal of Chemical Physics. 2006. DOI : 10.1063/1.2387163.Efficient, highly selective laser isotope separation of carbon-13
Applied Physics B-Lasers and Optics. 2006. DOI : 10.1007/s00340-006-2176-3.Electronic spectroscopy of cold, protonated tryptophan and tyrosine
Journal of the American Chemical Society. 2006. DOI : 10.1021/ja058383u.Infrared spectroscopy of hydrated amino acids in the gas phase: protonated and lithiated valine
Journal of the American Chemical Society. 2006. DOI : 10.1021/ja056079v.Vibrational overtone spectroscopy of jet-cooled methanol from 5000 to 14000 cm(-1)
Journal of Chemical Physics. 2005. DOI : 10.1063/1.1833353.Collisionally assisted, highly selective laser isotope separation of carbon-13
Journal of Chemical Physics. 2004. DOI : 10.1063/1.1822918.Infrared laser chemistry of trichlorosilane in view of silicon isotope separation
Journal of Physical Chemistry A. 2003. DOI : 10.1021/jp0356362.Collisionally enhanced isotopic selectivity in multiphoton dissociation of vibrationally excited CF3H
Journal of Chemical Physics. 2003. DOI : 10.1063/1.1524177.Nonlinear intensity dependence in the infrared multiphoton excitation and dissociation of methanol pre-excited to different energies
Journal of Chemical Physics. 2002. DOI : 10.1063/1.1501280.Isotopically selective infrared multiphoton dissociation of vibrationally excited SiH4
JOURNAL OF PHYSICAL CHEMISTRY A. 2002. DOI : 10.1021/jp015609g.Rotational and torsional analysis of the OH-stretch third overtone in (CH3OH)-C-13
JOURNAL OF MOLECULAR SPECTROSCOPY. 2002. DOI : 10.1006/jmsp.2001.8506.Torsion-rotation analysis of OH stretch overtone-torsion combination bands in methanol
Journal of Chemical Physics. 2002. DOI : 10.1063/1.1421357.Collision-free infrared multiphoton dissociation of silane
JOURNAL OF PHYSICAL CHEMISTRY A. 2000. DOI : 10.1021/jp002566f.Intramolecular energy transfer in highly vibrationally excited methanol. IV. Spectroscopy and dynamics of (CH3OH)-C-13
Journal of Chemical Physics. 2000. DOI : 10.1063/1.1323507.Intramolecular energy transfer in highly vibrationally excited methanol. III. Rotational and torsional analysis
Journal of Chemical Physics. 1999. DOI : 10.1063/1.479076.Intramolecular energy transfer in highly vibrationally excited methanol. II. Multiple time scales of energy redistribution
Journal of Chemical Physics. 1999. DOI : 10.1063/1.479075.Transient photocurrents in lead zirconate titanate thin films
Applied Physics Letters. 1998. DOI : 10.1063/1.120663.Highly efficient optically pumped NH3 laser with near diffraction limited output
REVIEW OF SCIENTIFIC INSTRUMENTS. 1998. DOI : 10.1063/1.1149247.Intramolecular energy transfer in highly vibrationally excited methanol .1. Ultrafast dynamics
Journal of Chemical Physics. 1997. DOI : 10.1063/1.475041.State-to-state studies of intramolecular dynamics and unimolecular reactions
BERICHTE DER BUNSEN-GESELLSCHAFT. 1997. DOI : 10.1002/bbpc.19971010305.Secondary time scales of intramolecular vibrational energy redistribution in CF3H studied by vibrational overtone spectroscopy
Journal of Chemical Physics. 1996. DOI : 10.1063/1.472482.ROTATIONAL STATE-SELECTED VIBRATIONAL OVERTONE SPECTROSCOPY OF JET-COOLED MOLECULES
Journal of Chemical Physics. 1995. DOI : 10.1063/1.469723.Vibrational Overtone Spectra of Jet‐Cooled CF3H by Infrared Laser Assisted Photofragment Spectroscopy
Berichte der Bunsen-gesellschaft. 1995. DOI : 10.1002/bbpc.19950990340.Multiple timescales in the intramolecular vibrational energy redistribution of highly excited methanol
Faraday Discussions. 1995. DOI : 10.1039/fd9950200167.Autres publications
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